BEDIAKO LAB
ELECTROCHEMISTRY OF 2D LAYERS | 2D MAGNETISM | TWISTRONICS
Publications
(º denotes equal author contribution)
(* denotes corresponding author)
Preprints (in review)
"Anomalous Hall effect from inter-superlattice scattering in a noncollinear antiferromagnet"
Xie, L.S.; Fender, S.S.; Mollazadeh, C.; Fang, W.; Frontzek, M.D.; Husremović, S.; Li, K.; Craig, I.M.; Goodge, B.H.; Erodici, M.P.; Gonzalez, O.; Denlinger J.P.; Ping Y.; Bediako, D.K.*
(Preprint available at arXiv:2411.08381)
"Modeling the Superlattice Phase Diagram of Transition Metal Intercalation in Bilayer 2H-TaS"
Craig, I. M.; Kim, B. J.; Limmer, D. T.; Bediako, D. K.; Griffin, S. M.*
(Preprint available at arXiv:2410.19664)
"Tailored topotactic chemistry unlocks heterostructures of magnetic intercalation compounds"
Husremović, S.; Gonzalez, O.; Goodge, B. H.; Xie, L. S.; Kong, Z.; Zhang, W.; Ryu, S. H.; Ribet, S. M.; Bustillo, K. C.; Song, C.; Ciston, J.; Taniguchi, T.; Watanabe, K.; Ophus, C.; Jozwiak, C.; Bostwick A.; Rotenberg, E.; Bediako, D. K.*
(Preprint available at arXiv:2406.15261)
Published/In Press
(46) "Considerations for extracting moiré-level strain from dark field intensities in transmission electron microscopy"
Craig, I. M.; Van Winkle, M.; Ophus, C.; Bediako, D. K.*
Journal of Applied Physics 2024, 136, 074301 (Preprint available at arXiv:2406.04515
(45) "Iron homo- and heterobimetallic complexes supported by a symmetrical dinucleating ligand"
Rios, P.; See, M. S.; Gonzalez, O.; Handford, R. C.; Nicolay, A.; Rao, G.; Britt, R. D.*; Bediako, D. K.*; Tilley, T. D.
Chemical Communications 2024, 60, 8912–8915.
(44) "Scanning electrochemical probe microscopy investigation of two-dimensional materials" (Review)
Adanigbo, P.; Romo-Jimenez, J.; Zhang, K.; Maroo, S.; Bediako, D. K.; Yu, Y.*
2D Materials 2024, 11, 032001
(43) "Engineering interfacial polarization switching in van der Waals multilayers"
Van Winkle, M.; Dowlatshahi, N.; Khaloo, N.; Iyer, M.; Craig, I. M.; Dhall, R.; Taniguchi, T.; Watanabe, K.; Bediako, D. K.*
Nature Nanotechnology 2024, 19, 751–757 (Preprint available at arXiv:2311.17300)
(42) "Local atomic stacking and symmetry in twisted graphene trilayers"
Craig, I. M.; Van Winkle, M.; Groschner, C.; Zhang, K.; Dowlatshahi, N.; Zhu, Z.; Taniguchi, T.; Watanabe, K.; Griffin, S. M.; Bediako, D. K.*
Nature Materials 2024, 23, 323–330 (Preprint available at arXiv:2303.09662)
(41) "Modulating the electrochemical intercalation of graphene interfaces with α-RuCl3 as a solid-state electron acceptor"
Nessralla, J.; Larson, D. T.; Taniguchi, T.; Watanabe, K.; Kaxiras, E.; Bediako, D. K.*
Nano Letters 2023, 23, 10334–10341 (Preprint available at arXiv:2308.06437)
(40) "Consequences and control of multi-scale order/disorder in chiral magnetic textures"
Goodge, B. H.;º Gonzalez, O.;º Xie, L.; Bediako, D. K.*
ACS Nano 2023, 17, 19865–19876
(39) "Encoding multistate charge order and chirality in endotaxial heterostructures"
Husremović, S.; Goodge, B. H.; Inzani, K.; Mier, A.; Ribet, S. M.; Bustillo, K. C.; Taniguchi, T.; Watanabe, K.; Ophus, C.; Griffin, S. M.; Bediako, D. K.*
Nature Communications 2023, 14, 6031
(38) "Near room-temperature intrinsic exchange bias in an Fe intercalated ZrSe2 spin glass"
Kong, Z.; Kaminsky, C. J.; Groschner, C. K.; Murphy, R. A.; Yu, Y.; Husremovic, S.; Xie, L. S.; Erodici, M. P.; Kim, R. S.; Yano, J.; Bediako, D. K.*
J. Am. Chem. Soc. 2023, 145, 20041–20052
(37) "Comparative electronic structures of the chiral helimagnets Cr1/3NbS2 and Cr1/3TaS2"
Xie, L. S.;º Gonzalez, O;º Li, K.; Michiardi, M.; Gorovikov, S.; Ryu, S. H.; Fender, S. S.; Zonno, M.; Jo, N. H.; Zhdanovich, S.; Jozwiak, C.; Bostwick, A.; Husremovic, S.; Erodici, M. P.; Mollazadeh, C.; Damascelli, A.; Rotenberg, E.; Ping, Y.; Bediako, D. K.*
Chem. Mater. 2023, 35, 7239–7251
(36) "Bridging structure, magnetism, and disorder in iron-intercalated niobium diselenide, FexNbSe2, below x = 0.25"
Erodici, M.; Mai, T. T.; Xie, L.; Li, S.; Fender, S. S.; Husremovic, S.; Gonzalez, O.; Hight Walker, A. R.; Bediako, D. K.*
J. Phys. Chem. C 2023, 127, 9787–9795.
(35) "Anomalous interfacial electron transfer kinetics in twisted trilayer graphene caused by layer-specific localization"
Zhang, K.; Yu, Y.; Carr, S.; Babar, M.; Zhu, Z.; Kim, B.; Groschner, K.; Khaloo, N.; Taniguchi, T.; Watanabe, K.; Viswanathan, V.; Bediako, D. K.*
ACS Central Sci. 2023, 9, 1119–1128.
(34) "Decoupling effects of electrostatic gating on electronic transport and interfacial charge-transfer kinetics at few-layer molybdenum disulfide"
Maroo, S.; Yu, Y.; Taniguchi, T.; Watanabe, K.; Bediako, D. K.*
ACS Nanoscience Au 2023, 3, 204–210.
(33) "Rotational and dilational reconstruction in transition metal dichalcogenide moiré bilayers"
Van Winkle, M.;º Craig, I. M.;º Carr, S.; Dandu, M.; Bustillo, K.; Ciston, J.; Ophus, C.; Taniguchi, T.; Watanabe, K.; Griffin, S.; Bediako, D. K.*
Nature Communications 2023, 14, 2989.
(32) "Mixed dimensionality weaves exotic behaviour into superlattices" (News & Views)
Goodge, B. H.;* Bediako, D. K.*
Nature (News & Views) 2022, 609, 38–39.
(31) "Tuning interfacial chemistry with twistronics" (Forum)
Yu, Y.; Van Winkle, M.; Bediako, D. K.*
Trends in Chemistry 2022, 4, 857–859.
(30) "Hard ferromagnetism down to the thinnest limit of iron-intercalated tantalum disulfide"
Husremovic, S.; Groschner, C. K.; Inzani, K.; Craig, I. M.; Bustillo, K.; Ercius, P.; Kazmierczak, N. P.; Syndikus, J.; Van Winkle, M.; Aloni, S.; Taniguchi, T.; Watanabe, K.; Griffin, S. M.; Bediako, D. K.*
J. Am. Chem. Soc. 2022, 144, 12167–12176 (Preprint available at https://arxiv.org/abs/2203.05747)
(29) "Structure and Magnetism of Iron- and Chromium-Intercalated Niobium and Tantalum Disulfides" (Perspective)
Xie, L.; Husremovic, S.; Gonzalez, O.; Craig, I. M.; Bediako, D. K.*
J. Am. Chem. Soc. 2022, 144, 9525−9542 (Preprint available at 10.26434/chemrxiv-2022-psldt)
(28) "Chloroaluminate anion intercalation in graphene and graphite: from 2D devices to aluminum-ion batteries"
Yoon, H;º Rezaee, M.;º Lee, Y. A.; Yim, K.; Tamarany, R.; Lee, C.-W.; McGraw, V. S.; Taniguchi, T.; Watanabe, K.; Kim, P.; Yoo, C.-Y.;* Bediako, D. K.*
Nano Letters 2022, 22, 1726–1733.
(27) "Tunable angle-dependent electrochemistry at twisted bilayer graphene with moiré flat bands"
Yu, Y; Zhang, K.; Parks, H.; Babar, M.; Carr, S.; Craig, I.; Van Winkle, M.; Lyssenko, A.; Taniguchi, T.; Watanabe, K.; Viswanathan, V.; Bediako, D. K.*
Nature Chemistry 2022, 14, 267–273 (Preprint available at https://arxiv.org/abs/2108.06826)
Highlighted in: Oluwasegun, J.; Unwin, P.R. "Let's twist electrochem" Nature Chemistry 2022, 14, 248-250.
(26) "Strain fields in twisted bilayer graphene"
Kazmierczak, N.P.;º Van Winkle, M.;º Ophus, C.; Bustillo, K. C.; Carr, S.; Brown, H. B.; Ciston, J.; Taniguchi, T.; Watanabe, K.; Bediako, D. K.*
Nature Materials 2021, 20, 956–963 (Preprint available at https://arxiv.org/abs/2008.09761).
Highlighted in: Haigh, S.; Gorbachev, R. "Magic under the microscope" Nature Materials 2021, 20, 908–909.
(25) "Entering Flatland in One Piece: Growth and Electronic Transport Measurements of Single Crystal Two-Dimensional Conductive MOFs" (First Reactions)
Van Winkle, M.; Bediako, D. K.*
ACS Central Sci. (First Reactions) 2021, 7, 14–16.
Prior to UC Berkeley (DKB's post-doctoral, graduate, & undergraduate research)
​
(24) Day, R. W.; Bediako, D. K.; Rezaee, M.; Parent, L. R.; Skorupskii, G.; Arguilla, M. Q.; Hendon, C. H.; Stassen, I.; Gianneschi, N. C.; Kim, P.; Dincă, M. ACS Central Sci., 2019, 5, 1959–1964.
"Single crystals of electrically conductive 2D MOFs: structural and electrical transport properties"
​
(23) Chaudary, K.; Tamagnone, M.; Rezaee, M.; Bediako, D. K.; Ambrosio, A.; Kim, P.; Capasso, F. Sci. Adv. 2019, 5, eaau7171.
“Engineering phonon polaritons in van der Waals heterostructures to enhance in-plane optical anisotropy”
​
(22) Brodsky, C. N.; Bediako, D. K.; Shi, C.; Keane, T. P.; Costentin, C.; Billinge, S. J. L.; Nocera, D. G. ACS Appl. Energy Mater. 2019, 2, 3–12.
“Proton–electron conductivity in thin films of a cobalt-oxygen evolving catalyst”
​
(21) Bediako, D. K.;º Rezaee, M.;º Yoo, H.; Larson, D. T.; Zhao, S.-Y.; Taniguchi, T.; Watanabe, K.; Brower-Thomas T.; Kaxiras, E.; Kim, P. Nature 2018, 558, 425–429.
“Heterointerface effects in the electrointercalation of van der Waals heterostructures”
​
(20) Zhao, S.-Y.; Elbaz, G. A.; Bediako, D. K.; Efetov, D. K.; Guo, Y.; Ravichandran, J.; Min, K.-A.; Hong, S.; Taniguchi, T.; Watanabe, K.; Brus, L. E.; Roy, X.; Kim, P. Nano Lett. 2018, 18, 460–466.
“Controlled electrochemical intercalation of graphene/h-BN van der Waals heterostructures”
​
(19) Li, N.;º Bediako, D. K.;º Hadt, R. G.; Hayes, D.; Kempa, T. J.; von Cube, F.; Bell, D. C.; Chen, L. X.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2017, 114, 1486–1491.
“Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films”
​
(18) Bediako, D. K.; Ullman, A. M.; Nocera, D. G. Catalytic Oxygen Evolution by Cobalt Oxido Thin Films. In Topics in Current Chemistry; Tuysuz, H. & Chan, C. K. Eds.; Springer Int. Publishing AG: Cham, Switzerland, 2016; pp. 173–213.
​
(17) Kempa, T. J.;† Bediako, D. K.;† Kim, S.-K.;† Park, H.-G.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A.2015, Proc. Natl. Acad. Sci. U.S.A. 2015, 112, 5309–5313.
“High-throughput patterning of photonic structures with tunable periodicity”
​
(16) Kempa, T. J.; Bediako, D. K.; Jones, E. C.; Lieber, C, M.; Nocera, D. G. J. Am. Chem. Soc. 2015, 137, 3739–3742.
“Facile, rapid, and large-area periodic patterning of semiconductor substrates with sub-micron inorganic structures”
​
(15) Torella, J. P.; Gagliardi, C. J.; Chen, J. S.; Bediako, D. K.; Colón, B.; Way, J. C.; Silver, P. A.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2015, 112, 2337–2342.
“Efficient solar-to-fuels production from a hybrid microbial-water-splitting catalyst system”
​
(14) Dogutan, D. K.; Bediako, D. K.; Graham, D. J.; Lemon, C. M.; Nocera, D. G. J. Porphyrins Phthalocyanines 2015, 19, 1–8.
“Proton-coupled electron transfer chemistry of hangman macrocycles: Hydrogen and oxygen evolution reactions”
​
(13) Ullman, A. M.; Liu, Y.; Huynh, M.; Bediako, D. K.; Wang, H.; Anderson, B. L.; Powers, D. C.; Breen, J. J.; Abruña, H. D.; Nocera, D. G. J. Am. Chem. Soc. 2014, 136, 17681–17688.
“Water oxidation by Co(II) impurities in Co(III)4O4 cubanes”
​
(12) Bediako, D. K.; Solis, B. H.; Dogutan, D. K.; Roubelakis, M. M.; Maher, A. G.; Lee, C. H.; Chambers, M. B.; Hammes-Schiffer, S.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2014, 111, 15001–15006.
“Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins”
​
(11) Huynh, M.; Bediako, D. K.; Liu, Y.; Nocera, D. G. J. Phys. Chem. C. 2014, 118, 17142–17152.
“Nucleation and growth mechanisms of an electrodeposited manganese oxide oxygen evolution catalyst”
​
(10) Huynh, M.; Bediako, D. K.; Nocera, D. G. J. Am. Chem. Soc. 2014, 136, 6002–6010.
“A functionally stable manganese oxide oxygen evolution catalyst in acid”
​
(9) Bediako, D. K.; Costentin, C.; Jones, E. C.; Nocera, D. G.; Savéant, J.-M. J. Am. Chem. Soc. 2013, 135, 10492−10502.
“Proton–electron transport and transfer in electrocatalytic films. Application to a cobalt-based O2-evolution catalyst”
​
(8) Farrow, C. L.; Bediako, D. K.; Surendranath, Y.; Nocera, D. G.; Billinge, S. J. L. J. Am. Chem. Soc. 2013, 135, 6403–6406.
“Intermediate-range structure of self-assembled cobalt-based oxygen evolution catalyst”
​
(7) Bediako, D. K.; Surendranath, Y.; Nocera, D. G. J. Am. Chem. Soc. 2013, 135, 3662−3674.
“Mechanistic studies of the oxygen evolution reaction mediated by a nickel−borate thin film electrocatalyst”
​
(6) Surendranath, Y.; Bediako, D. K.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2013, 109, 15617–15621.
“Interplay of oxygen evolution kinetics and photovoltaic power curves on the construction of artificial leaves”
​
(5) Bediako, D. K.; Lassalle-Kaiser, B.; Surendranath, Y.; Yano, J.; Yachandra, V. K.; Nocera, D. G. J. Am. Chem. Soc. 2012, 134, 6801–6809.
“Structure–activity correlations in a nickel–borate oxygen evolution catalyst”
​
(4) Roubelakis, M. M.; Bediako, D. K.; Dogutan, D. K.; Nocera, D. G. Energy Environ. Sci. 2012, 5, 7737–7740.
“Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins”
​
(3) Dogutan, D. K.; Bediako, D. K.; Teets, T. S.; Schwalbe, M.; Nocera, D. G. Org. Lett. 2010, 12, 1036–1039.
“Efficient microwave assisted synthesis of hangman porphyrins”
​
(2) McNitt, K. A.; Parimal, K.; Share, A. I.; Fahrenbach, A. C.; Witlicki, E. H.; Pink, M.; Bediako, D. K.; Plaisier, C. L.; Le, N.; Heeringa, L. P.; Vander Griend, D. A.; Flood, A. H. J. Am. Chem. Soc. 2009, 131, 1305–1313.
“Reduction of a redox-active ligand drives switching in a Cu(I) pseudorotaxane by a bimolecular mechanism”
​
(1) Vander Griend, D. A.; Bediako, D. K.; DeVries, M. J.; DeJong, N.A.; Heeringa, L. P.; Inorg. Chem. 2008, 47, 656–662.
“Detailed spectroscopic, thermodynamic and kinetic characterization of nickel(II) complexes with 2,2'-bipyridine and 1,10-phenanthroline attained via equilibrium-restricted factor analysis”