(† denotes equal author contribution)

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Publications from the Bediako Lab
(32) "Mixed dimensionality weaves exotic behavior into superlattices" (News & Views) Goodge, B. H.; Bediako, D. K.  Nature, 609, 38–39.
(31) "Tuning interfacial chemistry with twistronics" (Forum) Yu, Y.; Van Winkle, M.; Bediako, D. K.  Trends in Chemistry 2022, 4, 857–859.
(30)   "Hard ferromagnetism down to the thinnest limit of iron-intercalated tantalum disulfide"
Husremovic, S.; Groschner, C. K.; Inzani, K.; Craig, I. M.; Bustillo, K.; Ercius, P.; Kazmierczak, N. P.; Syndikus, J.; Van Winkle, M.; Aloni, S.; Taniguchi, T.; Watanabe, K.; Griffin, S. M.; Bediako, D. K. 
J. Am. Chem. Soc. 2022, 144, 12167–12176.

(Preprint available at

(29)   "Structure and Magnetism of Iron- and Chromium-Intercalated Niobium and Tantalum Disulfides" (Perspective)
Xie, L.; Husremovic, S.; Gonzalez, O.; Craig, I. M.; Bediako, D. K. 
J. Am. Chem. Soc. 2022, 144, 9525−9542. (Preprint available at 10.26434/chemrxiv-2022-psldt)
(28)    "Chloroaluminate anion intercalation in graphene and graphite: from two-dimensional devices to aluminum-ion batteries"
Yoon, H;† Rezaee, M.;† Lee, Y. A.; Yim, K.; Tamarany, R.; Lee, C.-W.; McGraw, V. S.; Taniguchi, T.; Watanabe, K.; Kim, P.; Yoo, C.-Y.; Bediako, D. K. 
 Nano Letters 2022, 22, 1726–1733. 
(27)     "Tunable angle-dependent electrochemistry at twisted bilayer graphene with moiré flat bands"
Yu, Y; Zhang, K.; Parks, H.; Babar, M.; Carr, S.; Craig, I.; Van Winkle, M.; Lyssenko, A.; Taniguchi, T.; Watanabe, K.; Viswanathan, V.; Bediako, D. K.
Nature Chemistry 2022, 14, 267–273. (Preprint available at
  Highlighted in: Oluwasegun, J.; Unwin, P.R. "Let's twist electrochem" Nature Chemistry 2022, 14, 248-250.
(26)     "Strain fields in twisted bilayer graphene"
Kazmierczak, N.P.;†  Van Winkle, M.;† Ophus, C.; Bustillo, K. C.; Carr, S.; Brown, H. B.; Ciston, J.; Taniguchi, T.; Watanabe, K.; Bediako, D. K.
Nature Materials 2021, 20, 956–963. (Preprint available at
Highlighted in: Haigh, S.; Gorbachev, R. "Magic under the microscope" Nature Materials 2021, 20, 908–909.
(25)     "Entering Flatland in One Piece: Growth and Electronic Transport Measurements of Single Crystal Two-Dimensional Conductive MOFs" (First Reactions)
Van Winkle, M.; Bediako, D. K. ACS Central Sci. 2021, 7, 14–16.
Post-doctoral, graduate, & undergraduate research

(24)     Day, R. W.; Bediako, D. K.; Rezaee, M.; Parent, L. R.; Skorupskii, G.; Arguilla, M. Q.; Hendon, C. H.; Stassen, I.; Gianneschi, N. C.; Kim, P.; Dincă, M. ACS Central Sci., 2019, 5, 1959–1964.

"Single crystals of electrically conductive 2D MOFs: structural and electrical transport properties"

(23)     Chaudary, K.; Tamagnone, M.; Rezaee, M.; Bediako, D. K.; Ambrosio, A.; Kim, P.; Capasso, F. Sci. Adv. 2019, 5, eaau7171.
“Engineering phonon polaritons in van der Waals heterostructures to enhance in-plane optical anisotropy”

(22)     Brodsky, C. N.; Bediako, D. K.; Shi, C.; Keane, T. P.; Costentin, C.; Billinge, S. J. L.; Nocera, D. G. ACS Appl. Energy Mater. 2019, 2, 3–12.
“Proton–electron conductivity in thin films of a cobalt-oxygen evolving catalyst”

(21)     Bediako, D. K.;  Rezaee, M.;  Yoo, H.; Larson, D. T.; Zhao, S.-Y.; Taniguchi, T.; Watanabe, K.; Brower-Thomas T.; Kaxiras, E.; Kim, P. Nature 2018, 558, 425–429.
“Heterointerface effects in the electrointercalation of van der Waals heterostructures”

(20)     Zhao, S.-Y.; Elbaz, G. A.; Bediako, D. K.; Efetov, D. K.; Guo, Y.; Ravichandran, J.; Min, K.-A.; Hong, S.; Taniguchi, T.; Watanabe, K.; Brus, L. E.; Roy, X.; Kim, P. Nano Lett. 2018, 18, 460–466.
“Controlled electrochemical intercalation of graphene/h-BN van der Waals heterostructures”

(19)     Li, N.;  Bediako, D. K.;  Hadt, R. G.; Hayes, D.; Kempa, T. J.; von Cube, F.; Bell, D. C.; Chen, L. X.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2017, 114, 1486–1491.
“Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films”

(18)     Bediako, D. K.; Ullman, A. M.; Nocera, D. G. Catalytic Oxygen Evolution by Cobalt Oxido Thin Films. In Topics in Current Chemistry; Tuysuz, H. & Chan, C. K. Eds.; Springer Int. Publishing AG: Cham, Switzerland, 2016; pp. 173–213.

(17)     Kempa, T. J.;  Bediako, D. K.;  Kim, S.-K.;  Park, H.-G.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A.2015, Proc. Natl. Acad. Sci. U.S.A. 2015112, 5309–5313.
“High-throughput patterning of photonic structures with tunable periodicity”

(16)     Kempa, T. J.; Bediako, D. K.; Jones, E. C.; Lieber, C, M.; Nocera, D. G. J. Am. Chem. Soc. 2015137, 3739–3742.
“Facile, rapid, and large-area periodic patterning of semiconductor substrates with sub-micron inorganic structures”

(15)     Torella, J. P.; Gagliardi, C. J.; Chen, J. S.; Bediako, D. K.; Colón, B.; Way, J. C.; Silver, P. A.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2015112, 2337–2342.
“Efficient solar-to-fuels production from a hybrid microbial-water-splitting catalyst system”

(14)     Dogutan, D. K.; Bediako, D. K.; Graham, D. J.; Lemon, C. M.; Nocera, D. G. J. Porphyrins Phthalocyanines 201519, 1–8.
“Proton-coupled electron transfer chemistry of hangman macrocycles: Hydrogen and oxygen evolution reactions”

(13)     Ullman, A. M.; Liu, Y.; Huynh, M.; Bediako, D. K.; Wang, H.; Anderson, B. L.; Powers, D. C.; Breen, J. J.; Abruña, H. D.; Nocera, D. G. J. Am. Chem. Soc. 2014136, 17681–17688.
“Water oxidation by Co(II) impurities in Co(III)4O4 cubanes”

(12)     Bediako, D. K.; Solis, B. H.; Dogutan, D. K.; Roubelakis, M. M.; Maher, A. G.; Lee, C. H.; Chambers, M. B.; Hammes-Schiffer, S.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2014111, 15001–15006.
“Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins”

(11)     Huynh, M.; Bediako, D. K.; Liu, Y.; Nocera, D. G. J. Phys. Chem. C. 2014118, 17142–17152.
“Nucleation and growth mechanisms of an electrodeposited manganese oxide oxygen evolution catalyst”

(10)     Huynh, M.; Bediako, D. K.; Nocera, D. G. J. Am. Chem. Soc. 2014136, 6002–6010.
“A functionally stable manganese oxide oxygen evolution catalyst in acid”

(9)     Bediako, D. K.; Costentin, C.; Jones, E. C.; Nocera, D. G.; Savéant, J.-M. J. Am. Chem. Soc. 2013135, 10492−10502.
“Proton–electron transport and transfer in electrocatalytic films. Application to a cobalt-based O2-evolution catalyst”

(8)     Farrow, C. L.; Bediako, D. K.; Surendranath, Y.; Nocera, D. G.; Billinge, S. J. L. J. Am. Chem. Soc. 2013135, 6403–6406.
“Intermediate-range structure of self-assembled cobalt-based oxygen evolution catalyst”

(7)     Bediako, D. K.; Surendranath, Y.; Nocera, D. G. J. Am. Chem. Soc. 2013135, 3662−3674.
“Mechanistic studies of the oxygen evolution reaction mediated by a nickel−borate thin film electrocatalyst”

(6)     Surendranath, Y.; Bediako, D. K.; Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2013109, 15617–15621.
“Interplay of oxygen evolution kinetics and photovoltaic power curves on the construction of artificial leaves”

(5)      Bediako, D. K.; Lassalle-Kaiser, B.; Surendranath, Y.; Yano, J.; Yachandra, V. K.; Nocera, D. G. J. Am. Chem. Soc. 2012134, 6801–6809.
“Structure–activity correlations in a nickel–borate oxygen evolution catalyst”

(4)     Roubelakis, M. M.; Bediako, D. K.; Dogutan, D. K.; Nocera, D. G. Energy Environ. Sci. 20125, 7737–7740.
“Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins”

(3)     Dogutan, D. K.; Bediako, D. K.; Teets, T. S.; Schwalbe, M.; Nocera, D. G. Org. Lett. 201012, 1036–1039.
“Efficient microwave assisted synthesis of hangman porphyrins”

(2)     McNitt, K. A.; Parimal, K.; Share, A. I.; Fahrenbach, A. C.; Witlicki, E. H.; Pink, M.; Bediako, D. K.; Plaisier, C. L.; Le, N.; Heeringa, L. P.; Vander Griend, D. A.; Flood, A. H. J. Am. Chem. Soc. 2009131, 1305–1313.
“Reduction of a redox-active ligand drives switching in a Cu(I) pseudorotaxane by a bimolecular mechanism”

(1)     Vander Griend, D. A.; Bediako, D. K.; DeVries, M. J.; DeJong, N.A.; Heeringa, L. P.; Inorg. Chem. 200847, 656–662.
“Detailed spectroscopic, thermodynamic and kinetic characterization of nickel(II) complexes with 2,2'-bipyridine and 1,10-phenanthroline attained via equilibrium-restricted factor analysis”